Production of radionuclides

General routes of manufacturing radionuclides for use in radiopharmaceutical preparations include the following general routes: nuclear fission reactions, charged particle induced reactions, neutron induced reactions and radionuclide generator systems. To produce a given radionuclide, the desired nuclear reaction must be identified and its feasibility evaluated, which depends on the cross section for the reaction of interest, energy and nature of the incident particle, chemical purity and availability of the target materials and radionuclidic composition after irradiation, among other factors.

Independently of the mode of production, the quality framework of Good Manufacture Practice (GMP) might be needed to be introduced at certain steps of the manufacturing process of a medical radionuclide, but not in all of them. For the step involving the nuclear reaction itself, usually described as “irradiation”, it is acceptable the involvement of non-GMP processes. By contrast, the more or less complex radiochemical processing required to obtain the desired radiochemical precursor, with radionuclide and radiochemical purity compatible with clinical uses, should comply with GMP guidelines. Noteworthily, radionuclide purification by mass separation processes, applied to produce several radionuclides available at PRISMAP’s portfolio, might also be considered as a non-GMP step because it is technologically very similar to cyclotron irradiations.

All these aspects are covered and discussed in the documents and sources provided below, which comprise information on the nuclear reactions and purification processes involved in the production of PRISMAP’s radionuclides.

PRISMAP Deliverable D4.1

 

PRISMAP workshop: “Radionuclide Production to Nuclear Medicine Clinical Applications: Regulatory Standards and Harmonisation of Quality and Safety”, held in February 2022, provided the basis for this document, which gives guidance for the early phase clinical research with novel radionuclides. It describes the current standards and a harmonised view of the European regulatory framework. The document complements the existing regulatory framework and is not considered legally binding.

Six chapters cover different aspects in radiopharmaceutical development. Each chapter includes dedicated guidelines and guidance documents from regulatory authorities and professional organisations, as well as references to scientific publications on the respective topic.

Related publications

 
Sc-43, Sc-44Material enrichment
  • DFT calculations of Ti-based molecules clustering with Ar for laser-based enrichment of stable isotopes.
    Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 541, 141–143 (2023). doi: 10.1016/j.nimb.2023.05.040. Archive: CDS
  • Thermal and Structural Characterization of a Titanium Carbide/Carbon Composite for Nuclear Applications.
    Materials 15, 8358 (2022). doi: 10.3390/ma15238358. Archive: PMC
Cu-64, Cu-67Cross sections La-135Yields & purification
  • Improved procedures for production and purification of 135La from enriched [135Ba]BaCO3 on a 16.5 MeV cyclotron.
    Applied Radiation and Isotopes 192, 110612 (2023). doi: 10.1016/j.apradiso.2022.110612. Archive: DTU Orbit
Tb-155, Tb-161Cross sections
  • Can we reach suitable 161Tb purity for medical applications using the 160Gd(d,n) reaction?.
    Applied Radiation and Isotopes 200, 110927 (2023). doi: 10.1016/j.apradiso.2023.110927. Archive: HAL
  • Study of terbium production from enriched Gd targets via the reaction 155Gd(d,2n)155Tb.
    Applied Radiation and Isotopes 201, 110996 (2023). doi: 10.1016/j.apradiso.2023.110996. Archive: HAL
  • Excitation functions of deuteron induced nuclear reactions on dysprosium targets for the production of the theranostic relevant isotopes of terbium.
    The European Physical Journal Plus 137, 1180 (2022). doi: 10.1140/epjp/s13360-022-03378-z. Archive: HAL
Tm-167Cross sections
  • Study of thulium-167 cyclotron production: a potential medically-relevant radionuclide.
    Frontiers in Chemistry 11, 1288588 (2023). doi: 10.3389/fchem.2023.1288588. Archive: BORIS
Tm-167Mass separation
  • Efficient Production of High Specific Activity Thulium-167 at Paul Scherrer Institute and CERN-MEDICIS.
    Frontiers in Medicine 8, 712374 (2021). doi: 10.3389/fmed.2021.712374. Archive: PMC
Ac-225Laser ionization & mass separation
  • Resonant laser ionization and mass separation of 225Ac.
    Scientific Reports 13, 1347 (2023). doi: 10.1038/s41598-023-28299-4. Archive: CDS

Cross sections

 

Experimental Nuclear Reaction Data (EXFOR) www-nds.iaea.org/exfor

Dedicated cross section for medical isotopes and monitors

Production yield estimators

Nuclear databases

 

TENDL is a nuclear data library which provides the output of the TALYS nuclear model code system for direct use in both basic physics and applications. The 11th version is TENDL-2021, which is based on both default and adjusted TALYS calculations and data from other sources (previous releases can also be found using that link) tendl.web.psi.ch/tendl_2021/tendl2021.html

JANIS (Java-based nuclear information software) is a display program designed to facilitate the visualisation and manipulation of nuclear data. Its objective is to allow the user of nuclear data to access numerical values and graphical representations without prior knowledge of the storage format www.oecd-nea.org/jcms/pl_39933/what-is-janis

Nuclear Monte Carlo codes

 

TALYS and the TALYS-related packages are open source software and datasets (GPL License) for the simulation of nuclear reactions) www-nds.iaea.org/talys

PHITS (Particle and Heavy Ion Transport code System) is a general purpose Monte Carlo particle transport simulation code developed under collaboration between JAEA, RIST, KEK and several other institutes. It can deal with the transport of all particles over wide energy ranges, using several nuclear reaction models and nuclear data libraries phits.jaea.go.jp